Silicon-29 nuclear magnetic resonance studies of aqueous silicate solutions. Part 5.—First-order patterns in potassium silicate solutions enriched with silicon-29
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 79 (10) , 1525-1538
- https://doi.org/10.1039/f29837901525
Abstract
This article describes the use of a very-high-field n.m.r. spectrometer, together with 29Si—{29Si} homonuclear decoupling, for the study of alkaline aqueous potassium silicate solutions enriched with silicon-29. Experimental details are given, together with results for first-order multiplet resonances and related singlets. The chemical structures of six silicate species have thus been determined.Keywords
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