Alkyl Substituent Effect in the Deprotonation of Unsymmetrical Ketones
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Physical Chemistry
- Vol. 100 (21) , 8827-8835
- https://doi.org/10.1021/jp953249p
Abstract
No abstract availableKeywords
This publication has 14 references indexed in Scilit:
- Mechanistic study of the collisionally activated dissociation of alkoxide anionsInternational Journal of Mass Spectrometry and Ion Processes, 1990
- An energy-resolved study of the fragmentation of some 2-substituted 2-propoxide ions and the rates of proton abstraction from acetoneInternational Journal of Mass Spectrometry and Ion Processes, 1989
- Regio‐specifity of the deprotonation of some aliphatic ketones and sulfones by NClJournal of Mass Spectrometry, 1989
- Stereochemical Criteria Providing Unambiguous Experimental Evidence for the intermediacy of ion/molecule complexes in the generation of enolates from gaseous alkoxides. Short communicationHelvetica Chimica Acta, 1989
- Mechanistic studies on gas-phase negative ion unimolecular decompositions. Alkoxide anionsJournal of the American Chemical Society, 1988
- Elimination of dihydrogen from collision-activated alkoxide negative ions in the gas phase. An ab initio and isotope effect studyJournal of the Chemical Society, Chemical Communications, 1984
- Isotope effects in fragmentationMass Spectrometry Reviews, 1983
- Optical rotary dispersion studies. 129. Conformational isotope effects and octant contributions of methyl-d3 and methyl (carbon-13) groups in cyclohexanoneJournal of the American Chemical Society, 1980
- Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicalsJournal of the American Chemical Society, 1977
- Acidity of Hydrocarbons. V. Stereochemistry and Mechanism of the Proton Exchange Reactions of Hydrocarbons in CyclohexylamineJournal of the American Chemical Society, 1962