The structures of lithium and magnesium derivatives of acetic acid ‘dianions’
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1014-1016
- https://doi.org/10.1039/c39850001014
Abstract
Ab initio and semi-empirical MNDO calculations indicate that monomeric dilithiated and bis-magnesyl derivatives of carboxylic acids (Ivanoff reagents) favour the 1,3-1,3′ doubly bridged structures generally found in metallated Y-conjugated dianion systems.Keywords
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