New universality class for gelation in a system with particle breakup
- 1 July 1988
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 38 (1) , 942-945
- https://doi.org/10.1103/physrevb.38.942
Abstract
We introduce a model of coagulation with single-particle breakoff, described by the kernels and . For above a critical value , the system either gels or reaches a steady-state size distribution, depending upon initial conditions. Below , gelation always occurs. At , the scaling exponent , which describes the large-size behavior of the steady-state size distribution, is frac72; rather than the usual value frac52;, indicating that this process belongs to a new universality class of gelation.
Keywords
This publication has 11 references indexed in Scilit:
- Cluster-size evolution in a coagulation-fragmentation systemPhysical Review Letters, 1987
- Kinetics of polymer degradationMacromolecules, 1986
- Kinetics of Coagulation with Fragmentation: Scaling Behavior and FluctuationsPhysical Review Letters, 1986
- Kinetics of reversible polymerizationJournal of Statistical Physics, 1984
- Pre- and post-gel size distributions in (ir)reversible polymerisationJournal of Physics A: General Physics, 1983
- Coagulation equations with gelationJournal of Statistical Physics, 1983
- Equilibrium and kinetic theory of polymerization and the sol-gel transitionThe Journal of Physical Chemistry, 1982
- Convergence to equilibrium in a system of reacting polymersCommunications in Mathematical Physics, 1979
- Dynamics of aerosol coagulation and condensationAIChE Journal, 1976
- Note on the Kinetics of Systems Manifesting Simultaneous Polymerization-Depolymerization PhenomenaThe Journal of Physical Chemistry, 1945