HYDRONIUM ION ABSORPTION IN THE REGION 1.7 µ
- 1 August 1959
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 37 (8) , 1249-1253
- https://doi.org/10.1139/v59-184
Abstract
Optical absorption of the hydronium ion in the region 1.7 µ was measured in solutions of nitric acid and perchloric acid in the concentration range 0.01 to 4.0 moles per liter. Above 0.1 molar the absorption did not follow Beer's Law, being smaller than predicted from the low concentration behavior. This enhanced transparency is attributed to a "negative absorption" band, associated with the change in solvent structure, found in this spectral region.Keywords
This publication has 8 references indexed in Scilit:
- THE SOLUBILITY OF URANIUM(IV) HYDROXIDE IN SOLUTIONS OF SODIUM HYDROXIDE AND PERCHLORIC ACID AT 25 °CCanadian Journal of Chemistry, 1957
- The Infrared Spectrum of the H3O+ Ion in Acid HydratesThe Journal of Chemical Physics, 1953
- The Variation of the Properties of Electrolytic Solutions with Degrees of Dissociation.Chemical Reviews, 1949
- The Dissociation of Strong Electrolytes.Chemical Reviews, 1946
- The Variation in the Structure of Water in Ionic SolutionsThe Journal of Chemical Physics, 1939
- The Raman Spectrum and the Structure of WaterJournal of the American Chemical Society, 1937
- THE EFFECTS OF SULFURIC ACID AND OF ZINC CHLORIDE ON THE MAIN RAMAN BAND OF WATERJournal of the American Chemical Society, 1937
- A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl IonsThe Journal of Chemical Physics, 1933