Ryanoids and related compounds. A total synthesis of 3-epiryanodine

Abstract
In the course of a preliminary investigation on the relationships between chemical structure of ryanoids and their affinity to the ryanodine (1) binding site, we have synthesized 3-epiryanodine (13) from anhydroryanodol (4), a key intermediate in our total synthesis of (+)-ryanodol (2).

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