Unprecedented Stereochemical Reversal from Alkyl to Aryl Substituents in the Johnson-Claisen Rearrangement of Methyl 3-Hydroxy-2-methylenealkanoates
- 1 August 1996
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1996 (08) , 747-748
- https://doi.org/10.1055/s-1996-5524
Abstract
An unprecedented stereochemical reversal from alkyl to aryl substituents in the Johnson-Claisen rearrangement of methyl 3-hydroxy-2-methylenealkanoates with triethyl orthoacetate with a plausible mechanism has been described.Keywords
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