Novel stereoselective syntheses of chiral 2,6-dideoxy-6,6,6-trifluoro sugars via enzymatic resolution of trifluoromethylated propynylic alcohol
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 51-52
- https://doi.org/10.1039/c39950000051
Abstract
All stereoisomers of homochiral 2,6-dideoxy-6,6,6-trifluoro sugars are conventionally synthesized from the same optically pure CF3-containing propynylic alcohol via the novel one-pot reaction of 2-bromo-3,3,3-trifluoropropene, followed by optical resolution by enzymatic esterification.Keywords
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