Synthesis of chiral allylic alcohols by the reaction of chiral titanium–alkyne complexes with carbonyl compounds
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1725-1726
- https://doi.org/10.1039/cc9960001725
Abstract
Chiral titanium–alkyne complexes derived from chlorotris[(–)-menthoxy]titanium/2 PriMgCl and alkynes react with aldehydes to afford optically active allylic alcohols in up to 38% ee.Keywords
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