Vibrational and electronic spectra of transition-metal carbonyl complexes. Part I. Infrared spectra of decacarbonyldimanganese and its derivatives
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 695-699
- https://doi.org/10.1039/j19660000695
Abstract
Precise infrared spectra of the compounds Mn2(CO)10 and Mn2(CO)8L2[L = PF3, P(OPh)3, AsPh3, PPh3, and PEt3] have been measured. Solvent effects in the C–O stretching region are observed and their significance discussed. Bands ascribed to M–C and C–O stretching vibrations correlate in the expected way.Keywords
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