Preparation of Bis(Dialkylphosphorodithioato)Dioxo-(Triphenylphosphine Oxide)Uranium(VI) Complexes
- 1 January 1976
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 6 (2) , 125-132
- https://doi.org/10.1080/00945717608057349
Abstract
The title compounds of the general formula UO2(S2PR2)2- OPPh3 (R=Oalkyl, Me, Ph) were prepared from dioxouranium(VI) diacetate and dialkylphosphorodithioic acids or dithiophosphinic acids in the presence of triphenylphosphine oxide. The compounds were characterised by analysis, infrared and electronic spectroscopy.Keywords
This publication has 8 references indexed in Scilit:
- Transition metal dithio- and diselenophosphate complexesPublished by Springer Nature ,2006
- Chemistry of the uranyl group. Part IV. Preparation and properties of triphenyl-phosphine and -arsine oxide complexes of uranyl dithioacetate and dithiobenzoate, and the structure of bis(dithioacetato)dioxo-(triphenylphosphine oxide)uranium(VI)J. Chem. Soc., Dalton Trans., 1972
- Metallkomplexe der Phosphinsäuren, IX. Ligandenfeldparameter von Chrom(III)‐dithiophosphinato‐KomplexenEuropean Journal of Inorganic Chemistry, 1972
- Uranyl chelate complexesInorganica Chimica Acta Reviews, 1971
- Isomere uranyl-chelate mit dithiolat-ligandenInorganic and Nuclear Chemistry Letters, 1971
- Chemistry of the uranyl group. III. Preparation, properties, and crystal structure of the isomorphous pair UO2((C2H5)3NCS2)2(C6H5)3AsO and UO2((C2H5)2NCS2)2(C6H5)3POInorganic Chemistry, 1970
- The Reaction of Uranyl Ion with Xanthates and DiethyldithiocarbamateJournal of the American Chemical Society, 1956
- Aromatic Phosphinic Acids and Derivatives. I. Diphenylphosphinodithoic Acid and Its DerivativesJournal of the American Chemical Society, 1955