β-AMINOCROTONONITRILE: I. GEOMETRICAL ISOMERISM AND SOME REACTIONS
Open Access
- 1 February 1965
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 43 (2) , 332-336
- https://doi.org/10.1139/v65-044
Abstract
The low-melting form of β-aminocrotononitrile is a mixture of two components, one of which is the high-melting isomer. Isomerization reactions between the high- and low-melting forms occur very easily, reactions in solution being subject to acid–base catalysis. Self-condensation of β-aminocrotononitrile gives 4-amino-1,3-dicyano-2-methylpenta-1,3-diene which readily cyclizes to 2-amino-5-cyano-4,6-lutidine.Keywords
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