Alkyne isomerization reagents: mixed alkali metal amides
- 1 July 1984
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 62 (7) , 1333-1334
- https://doi.org/10.1139/v84-224
Abstract
Addition of sodium and potassium alkoxides, particularly potassium tert-butoxide, to the lithium salts of either 1,2-diaminoethane or 1,3-diaminopropane afford alkyne isomerization reagents that effect triple bond migration to the end of a methylene chain under milder conditions and in higher yield than do previously reported reagents.Peer reviewed: YesNRC publication: YeKeywords
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