Control of the regioselectivity of N-nucleophile addition to N-carbonyl protected dehydroalanines: a model for the ammonia-lyase enzymes
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 1061-1062
- https://doi.org/10.1039/c39950001061
Abstract
The regioselectivity of the addition of N-nucleophiles to N-carbonyl protected dehydroalanine derivatives, β-conjugate addition vs. α-imine capture, can be controlled completely by varying the N-protecting group, or, the carboxy protecting group thereby providing a model for the chemistry of dehydroalanine residues within enzymes.Keywords
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