Isolation of η2-(C,C) ketene complexes of nickel from the reactions of nickelacyclobutane complexes with carbon monoxide
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 850-851
- https://doi.org/10.1039/c39850000850
Abstract
The η2(C,C) ketene complex [Ni(CH2 CO)(PPh3)2], a model complex for homogeneous CO reduction, was isolated by carbonylation of nickelacyclobutane complexes or by the reaction of [Ni(PPh3)4] with CH2Br2 in the presence of Zn followed by carbonylation.Keywords
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