Abstract
Electrochemical oxidation‐reduction processes of the electrode in concentrated alkaline solutions were investigated by using a rotating ring‐disk electrode as well as a stationary electrode. Results support the mechanism that the anodic oxidation of Cd to in the active potential range proceeds entirely through the dissolution‐precipitation sequence, while the cathodic reduction of takes place both through the solution phase and by a direct solid‐state mechanism. * Electrochemical Society Active Member.

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