Synthesis and X-ray structure of a cyclopropane precursor alkene–carbene complex of tungsten in which the two functions are parallel
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 574-576
- https://doi.org/10.1039/c39840000574
Abstract
Photolysis of pentacarbonyl pent-4-enyl (methoxy)carben tungsten(4) at low temperature affords a new chelated alkene–carbene complex (5) in which, according to an X-ray analysis, the alkene and the carbene functions are parallel, and which decomposes to give the expected cyclopropane (7).Keywords
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