Evidence for a “foiled methylene” in the reactions of bicyclo[3,3,1]non-2-en-9-ylidene
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 8,p. 503-504
- https://doi.org/10.1039/c29700000503
Abstract
The carbene (1) reacts intramolecularly in a way strongly suggestive of preliminary interaction with the double bond; and, although cyclopropane formation is prevented by geometric factors, the “foiled methylene” determines the ultimate products.Keywords
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