Derivation of Molecular Relaxation Parameters of an Isomeric Relaxation
- 1 January 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (1) , 151-153
- https://doi.org/10.1063/1.1840365
Abstract
The expressions for molecular parameters ΔH° and ΔG° are obtained in the presence of volume changes ΔV/V between the isomeric states and the results are used in investigating the influence of the volume changes on the molecular parameters ΔH°, ΔG°, and ΔS°. The present calculations show that for those liquids for which Cp/αRT is large, the molecular parameters are influenced considerably by the volume changes.Keywords
This publication has 4 references indexed in Scilit:
- Ultrasonic Relaxation and Axial—Equatorial Isomerization in Methylcyclohexane. IIThe Journal of Chemical Physics, 1965
- Ultrasonic Relaxation and Cis—Trans Isomerization in Isopropyl FormateThe Journal of Chemical Physics, 1965
- Absorption of Ultrasonic Waves in Pure MethylcyclohexaneThe Journal of Chemical Physics, 1962
- Ultrasonic Relaxation and Axial-Equatorial Isomerization in Methyl CyclohexaneThe Journal of the Acoustical Society of America, 1961