New microporous coordination polymer affording guest-coordination sites at channel wallsElectronic supplementary information (ESI) available: Fig. S1: XRPD patterns of (a) simulation, (b) 2 and (c) 3. See http://www.rsc.org/suppdata/cc/b1/b108695b/
- 7 January 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 222-223
- https://doi.org/10.1039/b108695b
Abstract
Utilization of a metalloligand, {[Cu(2,4-pydca)2(H2O)]·2Et3NH} (1) (2,4-pydca = pyridine-2,4-dicarboxylate), as a building unit provides a novel porous coordination polymer, {[ZnCu(2,4-pydca)2(H2O)3(DMF)]·DMF}n (2), in which the Zn(II) ion at the node of the network acts as a linker and the Cu(II) ion in the channel wall is available for guest-coordination.Keywords
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