Ground State ofMonolayers Adsorbed on Inert Substrate
- 1 February 1971
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 3 (2) , 691-696
- https://doi.org/10.1103/physreva.3.691
Abstract
We investigate the properties of a system of atoms at the absolute zero of temperature interacting via a Lennard-Jones potential, and constrained to motion in two dimensions by an otherwise inert substrate. Results of a semiclassical calculation indicate that the ground state is that of a self-bound liquid. It further indicates that a close-packed-solid configuration is not self-bound. A quantum-mechanical variational calculation is performed to obtain an upper bound on the energy of the system. A result of -0.61 °K per particle is obtained at a density of 0.035 . The relationship between this calculation and recent experiments on monolayers is briefly discussed.
Keywords
This publication has 19 references indexed in Scilit:
- Substrate-Mediated Interaction between Adsorbed AtomsPhysical Review A, 1970
- Heat Capacities of SubmonolayerandAdsorbed on Ar-Plated CopperPhysical Review A, 1970
- Paired-Phonon Analysis for the Ground State and Low Excited States of Liquid HeliumPhysical Review B, 1969
- Three-phonon vertex in the description of the ground state of liquid He4Annals of Physics, 1969
- Quantum Theory of Helium-4 MonolayersPhysical Review B, 1969
- Statistical Mechanics of Monolayers of Bose and Fermi Atoms Adsorbed on Crystalline SurfacesPhysical Review B, 1968
- Ground State of Liquid Helium-4 and Helium-3Physical Review B, 1967
- Perturbation method for low states of a many-particle boson systemAnnals of Physics, 1961
- Contribution to the quantum-mechanical theory of the equation of state and the law of corresponding states. Determination of the law of force of heliumPhysica, 1938
- Debije-scherrer exposures of liquid heliumPhysica, 1938