Synthesis and some reactions of the N-Tosyl derivative of indoles and 2,3-Dihydrocarbazol-4(1H)-one

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Abstract
The preparation and some reactions of the N-tosyl derivative of 3-(2?- nitropropenyl)indole (1), indole-3-carbaldehyde (2), indole-3- glyoxylamide (3), and 2,3-di-hydrocarbazol-4(1H)-one (7) are described. The N-tosylnitropropenyl derivative (1) was converted into α-methyl-1- tosyltryptamine, and the reaction of 2,3-dihydro-9-tosyl-carbazol-4(1H)-one (7) with ethoxyethynylmagnesium bromide and in the Mannich and Cope-Knoevenagel reactions are described.

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