ELECTROPHILIC SUBSTITUTIONS OF OLEFINIC HYDROGENS II. ACYLATION OF VINYL ETHERS AND N-VINYL AMIDES
- 5 May 1976
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 5 (5) , 499-502
- https://doi.org/10.1246/cl.1976.499
Abstract
Reactions of vinyl ethers, N-vinyl carboxamides and N-vinyl sulfonamides with trifluoroacetic (or trichloroacetic) anhydride occurred quite easily at room temperature to give corresponding β-trifluoro- or trichloroacetylated compounds in high yields. Reactions with a mixed anhydride, CH3COOCOCF3, gave trifluoroacetylated compounds in high yields, acetyl compounds being not produced.This publication has 1 reference indexed in Scilit:
- New reaction of trithioorthoacetates. Reaction with acylating reagentsThe Journal of Organic Chemistry, 1975