Epoxidation of Olefms with Molecular Oxygen and Alcohol Catalyzed by Bis(2-alkyl-1,3-diketonato)oxovanadium(IV)
- 1 September 1990
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 19 (9) , 1657-1660
- https://doi.org/10.1246/cl.1990.1657
Abstract
By combined use of molecular oxygen (oxidant) and secondary or primary alcohol (reductant) in the presence of a catalytic amount of bis(2-alkyl-1,3-diketonato)oxovanadium(IV) complexes, norbornene analogues are monooxygenated into the corresponding epoxides in good yields.Keywords
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