New methods for studying the mechanism of the π,σ-reaction in allylic metal complexes
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 6,p. 365-366
- https://doi.org/10.1039/c29700000365
Abstract
The n.m.r. spectrum of the compound (π-C4H7)PdCl(PPhMeMe′) reveals two simultaneous interchange reactions—interchange of the two nonequivalent methyl groups and interchange of allyl protons (3) and (4)—thus proving that the intermediate of the (3)–(4) interchange reaction contains a σ-bonded methyllyl group.Keywords
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