Determination of Residues of Alachlor and Its Metabolite in Corn, Soybeans, and Potatoes as Heptafluorobutyryl-2,6-Diethylaniline

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Abstract
Alachlor [2-chloro-2'6'-diethyl-N-(methoxymethyl)acetanilide] was determined by hydrolysis to 2,6-diethylaniline with 6N HC1 and quantitation of the heptafluorobutyryl derivative by gas chromatography with electron capture detection. 2,6-Diethylaniline was isolated from the hydrolysate by steam distillation, derivatized with heptafluorobutyric anhydride, and the derivative was purified by chromatography on silicic acid with 60% toluene in hexane as eluant. Recoveries from potatoes, soybeans, and corn spiked at levels from 3 to 26 ppb averaged 81,90, and 96% respectively.