NN′-dialkoxy-NN′-bis(trifluoromethyl)hydrazines, novel products from the reaction of alkoxyl radicals with trifluoronitrosomethane
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2344-2346
- https://doi.org/10.1039/p19740002344
Abstract
Alkoxyl radicals, generated by nitrite photolysis, react with trifluoronitrosomethane to yield NN′-dialkoxy-NN′-bis-(trifluoromethyl)hydrazines. An 18O-labelling experiment indicated complete retention of the alkoxy-oxygen atom. When the products are heated with thioglycolic acid, cracking leads to the hydroxylamines, RO·NH·CF3. For the case where R is 1-adamantyl, further stepwise conversion into O-(1-adamantyl)hydroxylamine has been achieved.Keywords
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