Copper(I) salt mediated 1,4-reduction of α,β-unsaturated ketones using hydrosilanes
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2159-2160
- https://doi.org/10.1039/a706032g
Abstract
Reduction of α,β-unsaturated ketones with HSiPhMe2 in the presence of CuF(PPh3)3·2EtOH proceeds in a 1,4-selective manner to give the corresponding saturated ketones in excellent yields.Keywords
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