Asymmetrized 2-Methyl-1,3-propanediol and Its Equivalents: Preparation and Synthetic Applications
- 1 January 1993
- journal article
- review article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1993 (11) , 1029-1056
- https://doi.org/10.1055/s-1993-25991
Abstract
This review describes the methods of enantioselective preparation and the main synthetic elaborations of asymmetrized 2-methyl-1,3-propanediol 1 and of its synthetic equivalents. 1 Introduction 2 Preparation 3 Functional Group Manipulation of β-Hydroxy-α-methylpropionic Acid Derivatives 4 Elongation Through Nucleophilic Substitution 5 Elongation Through Electrophilic Substitution 6 Elongation Through Olefination 7 Elongation Through Nucleophilic Addition 8 Miscellaneous ElaborationsKeywords
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