Pentaco-ordinate silicon derivatives:1H n.m.r. evidence
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 892-894
- https://doi.org/10.1039/c39800000892
Abstract
The 1H n.m.r. spectra of o-(Me2NCH2)C6H4SiX2R and o-(Me2NCH2)C6H4SiXR1R2 indicate that the intramolecular Si–N co-ordination is controlled by the ability of the Si–X bond to be stretched and substituted with inversion of configuration.Keywords
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