Dalton communications. Reactions of co-ordinated phosphines and arsines. Iron(II)-facilitated syntheses of 1-phenylphosphetane and 1-phenylarsetane
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 10,p. 1751-1752
- https://doi.org/10.1039/dt9920001751
Abstract
Phenylphosphine in the complex (R*, R*)-(±)-[Fe(η-C5H5){C6H4(PMePh)2-1,2}(PH2Ph]PF6 was treated with 1,3-dibromopropane in the presence of KOBut to give 1-phenylphosphetane; similarly, (±)-(3-chloropropyl)phenylarsine was converted into 1-phenylarsetane.Keywords
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