The Transformations of Dimeric Tri-O-acetyl-2-deoxy-2-nitroso-α-D-hexopyranosyl Chlorides in Dimethylformamide
- 1 January 1973
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 51 (1) , 1-6
- https://doi.org/10.1139/v73-001
Abstract
The dimeric nitrosyl chloride adducts of tri-O-acetyl-1,5-anhydro-2-deoxy-D-arabino-hex-1- and D-lyxo-hex-1- enitols (glycals) dissociate in dimethylformamide to the monomeric forms which rapidly isomerize to the corresponding tri-O-acetyl-2-oximino-α-D-hexopyranosyl chlorides. Evidence is provided for the dehydrochlorination of these latter compounds to highly reactive tri-O-acetyl-1,5-anhydro-2-deoxy-2-nitroso-D-hex-1-enitols.Keywords
This publication has 0 references indexed in Scilit: