cis-Isomer of the C26marine sterol 24,24-dimethyl-5α-chol-22-en-3β-ol

Abstract
The Δ22cis- and trans-C26 sterols (1) and (2) from a Wittig synthesis have been separated; the properties of the cis-isomer (1) may be explained by the obstruction to the free rotation of the side chain.

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