The dissociation constants of some aliphatic amines in water and methanol‐water mixtures at 25°
- 1 January 1960
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 79 (7) , 731-736
- https://doi.org/10.1002/recl.19600790709
Abstract
The dissociation constants of some primary aliphatic amines were measured in water and in methanol‐water mixtures at 25°. These dissociation constants (K* = a*Ha*B/a*HB ) show a maximum at 60‐80% methanol. This maximum is ascribed to the unequal influence of the methanol content of the solvent on γ0,H and γ0,HB.Keywords
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