New Methods and Reagents in Organic Synthesis; 73.1Trimethylsilyldiazomethane: A Convenient Reagent for the Conversion of Aliphatic Aldehydes to the Homologous Methyl Ketones
- 1 January 1988
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1988 (03) , 228-229
- https://doi.org/10.1055/s-1988-27522
Abstract
Trimethylsilyldiazomethane reacts smoothly with aliphatic aldehydes in the presence of magnesium bromide (1.5 equiv) to give homologous methyl ketones after direct treatment with 10% hydrochloric acid/methanol (1:1).Keywords
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