Thermal Decomposition of Ozone
- 15 May 1971
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 54 (10) , 4455-4459
- https://doi.org/10.1063/1.1674697
Abstract
The thermal decomposition of ozone was studied from 988–1400°K, and the rate constant for O3 + M → O2 + M was obtained. The results are compared to other studies and to a theoretical calculation (HRRKM). The results may indicate a breakdown in the Boltzmann statistically based HRRKM theory applied to ozone at temperatures above 1060°K and, therefore, point to the increasing importance of vibrational population as the rate‐controlling process.Keywords
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