Abstract
The absolute configurations of diastereoisomeric 1-phenylethyl p-tolyl sulphoxides have been established by o.r.d. and c.d. observations and these are in agreement with those obtained from chemical correlations. The stereochemistry of the oxidation of 1-phenylethyl p-tolyl sulphide to the sulphoxides is discussed in the light of the observed isomer distributions.

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