NEW DIRECTED CROSS-ALDOL REACTION USING 9-TRIFLUOROMETHYLSULFONYL-9-BORABICYCLO[3.3.1]NONANE
- 5 February 1977
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 6 (2) , 153-154
- https://doi.org/10.1246/cl.1977.153
Abstract
A directed cross-aldol reaction between two different carbonyl compounds by using 9-trifluoromethylsulfonyl-9-borabicyclo[3.3.1]nonane and tertiary amine is described. The reaction of methyl ketones with the other carbonyl compounds takes place in regiospecific manner to afford the corresponding cross-aldols in good yields through intermediates, 9-(1-methyl-1-alkenyl)oxy-9-borabicyclo[3.3.1]nonanes.Keywords
This publication has 1 reference indexed in Scilit:
- NEW CROSS-ALDOL REACTION Via VINYLOXYBORANESChemistry Letters, 1976