Carbon nanocapsules and single-layered nanotubes produced with platinum-group metals (Ru, Rh, Pd, Os, Ir, Pt) by arc discharge
- 1 September 1996
- journal article
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 80 (5) , 3062-3067
- https://doi.org/10.1063/1.363166
Abstract
Encapsulation of platinum‐group metals (Ru, Rh, Pd, Os, Ir, Pt) within carbon nanocapsules and synthesis of single‐layered (SL) carbon nanotubes by arc evaporation of metal/carbon composites have been studied. Transmission electron microscopy revealed that all the platinum‐group metals, forming small particles (10–200 nm in diameter), were encapsulated within multilayered graphitic cages. Particles trapped in the cages were single‐domain crystallites in normal metallic phases. Rh, Pd, and Pt showed catalytic activity for growing SL carbon tubes, but the other metals did not. Bundles of dense SL tubes with diameter 1.3–1.7 nm were extruding radially from metal particles for Rh and Pd; the sizes of core particles were 20–30 nm for Rh, and 50–200 nm for Pd. In the case of Pt, one or a few SL tubes (typically 1.3–2.0 nm in diameter and sometimes ∼3 nm) grew from a tiny particle (∼10 nm).This publication has 17 references indexed in Scilit:
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