Short Enantioselective Syntheses of Both 2,7-Dimethyl-1,6-dioxaspiro[4.6]undecane and 2,7-Diethyl-1,6-dioxaspiro[4.6]undecane Using Functionalized Nitroalkane Synthons
- 31 December 2000
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 2000 (04) , 537-540
- https://doi.org/10.1055/s-2000-6370
Abstract
ω-Nitro ketoaliphatic compounds 3a and 3b, prepared by a new and efficient route, have been elaborated to short syntheses of both 2,7-dimethyl-1,6-dioxaspiro[4.6]undecane, [(2S,5R,7S)-1a] and 2,7-diethyl-1,6-dioxaspiro[4.6]undecane [(2S,5R,7S)-1b], the pheromones produced by Andrena haemorrhoa and Andrena wilkella, respectively.Keywords
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