Evidence for a direct bonding interaction between titanium and a β-C–H moiety in a titanium–ethyl compound; X-ray crystal structure of [Ti(Me₂PCH₂CH₂PMe₂)EtCl₃]

1 January 1982

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 14,p. 802-803
https://doi.org/10.1039/c39820000802

Abstract

The X-ray crystal structure of [Ti(Me₂PCH₂CH₂PMe₂)EtCl₃](1) shows that the Ti–C–C angle and the Ti–C(methyl) distance of the Ti–Et moiety are 85.9(6)° and 2.516(10)Å, respectively and that the Ti–H–C (methyl) distances are 2.29(Ti–H) and 1.02(H–C)Å a direct bonding interaction between the titanium atom and the β-C–H system is proposed.

Keywords

TITANIUM

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Evidence for a direct bonding interaction between titanium and a β-C–H moiety in a titanium–ethyl compound; X-ray crystal structure of [Ti(Me2PCH2CH2PMe2)EtCl3]

Abstract

Keywords

Evidence for a direct bonding interaction between titanium and a β-C–H moiety in a titanium–ethyl compound; X-ray crystal structure of [Ti(Me₂PCH₂CH₂PMe₂)EtCl₃]