Four-co-ordinate iridium(I) cations and the ligand dependence of oxygen uptake: the crystal structure of [Ir(PPh2CH3)4]BF4
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 14,p. 758-759
- https://doi.org/10.1039/c29710000758
Abstract
Four-co-ordinate iridium(I) cations containing various combinations of the ligands, CO, MeCN, Me2SO, PPh3, PPh2Me, and PPh2Et are described including an X-ray structural analysis of [Ir(PPh2Me)4]BF4: the ability of these cations to co-ordinate oxygen is found to be sensitive to steric factors.Keywords
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