Lattice dynamics of ferroelectric NaNO 2 by two-phonon Raman scattering and infrared absorption

Abstract
Two-phonon spectra of Raman scattering and infrared absorption of NaNO2 crystals were obtained and interpreted. Spectroscopic data were compared with the data on inelastic neutron scattering. A new vibration with 65 cm−1 frequency was observed which was not found in the first-order Raman spectra and neutron scattering. Anomalous temperature dependence of this band is supposed to be connected with structural changes in the crystal lattice in the vicinity of ferroelectric transition.

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