Synthesis of optically active η6-benzene–ruthenium complexes
- 1 January 1977
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 488-489
- https://doi.org/10.1039/c39770000488
Abstract
The first examples of optically active arene–ruthenium complexes (+)-(1) and (–)-(1), prepared by the stepwise reaction of benzene(dichloro)ruthenium dimer with dimethylmercury and (R)-(+)-Ph2-PNHCH(Me)Ph and separated by chromatography, have stable configurations even in solution at 60 °C.Keywords
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