Synthesis and structure of α-diazomethyl palladium σ-complexes; X-ray crystal structure of chloro[diazo(ethoxycarbonyl)methyl]bistriphenylphosphinepalladium
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 450-451
- https://doi.org/10.1039/c39790000450
Abstract
Syntheses of (R1 3P)2ClPdC(N2)R2(1) and (R1 3P)2Pd[C(N2)R2]2(2), the first α-diazomethyl complexes of group 8 transition metals, are reported; their structures were determined from spectroscopic data and by X-ray crystallography of chloro[diazo(ethoxycarbonyl)methyl]bistriphenylphosphinepalladium (1a).Keywords
This publication has 0 references indexed in Scilit: