Atomic Bethe-Goldstone Equations. II. The Ne Atom
- 5 March 1967
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 155 (1) , 56-58
- https://doi.org/10.1103/physrev.155.56
Abstract
The nonrelativistic electronic energy of is computed by the variational solution of generalized Bethe-Goldstone (BG) equations. The sum of all two-particle net energy increments (pair correlation energies) is -0.3822 atomic units (a.u.), or 97.3% of the empirical correlation energy. The three- and four-particle net energy terms expected to be most important are computed and found to be smaller than 0.001 a.u. The computed pair correlation energies are analyzed in terms of symmetries induced in the BG equations, and are found to be represented well within the accuracy of the present calculations by the somewhat smaller number of parameters needed to characterize the and eigenstates of all possible eight-particle subsystems of the ten-electron Hartree-Fock reference state.
Keywords
This publication has 16 references indexed in Scilit:
- Atomic Bethe-Goldstone Equations. I. The Be AtomPhysical Review B, 1967
- Many-Electron Theory of Atoms and Molecules. V. First-Row Atoms and Their IonsThe Journal of Chemical Physics, 1964
- Correlation Energy for Atomic SystemsThe Journal of Chemical Physics, 1963
- Many-Electron Theory of Atoms and Molecules. IIThe Journal of Chemical Physics, 1962
- Many-Electron Theory of Atoms and Molecules. I. Shells, Electron Pairs vs Many-Electron CorrelationsThe Journal of Chemical Physics, 1962
- Atomic Wave Functions for the Ground States of Na+, Ne, and F-The Journal of Chemical Physics, 1961
- Effect of a repulsive core in the theory of complex nucleiProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1957
- Two-Body Forces and Nuclear Saturation. III. Details of the Structure of the NucleusPhysical Review B, 1955
- Nuclear Saturation and Two-Body Forces. II. Tensor ForcesPhysical Review B, 1954
- Electronic wave functions VIII. A calculation of the ground states Na + , Ne and F -Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1952