The cyclometallation of benzoic acid and the X-ray crystal structure of [C5Me5Ir(O2CC6H4)(Me2SO)]
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 770-771
- https://doi.org/10.1039/c39850000770
Abstract
The complexes [C5Me5M(C6H4CO2)(Me2SO)](1a, M = Rh; 1b, M = Ir), and [(p-cymene)Os(C6H4CO2)(Me2SO)], containing cyclometallated benzoic acid, have been prepared and characterised; carbonylation of (1a) yields phthalic anhydride.Keywords
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