Exchange perturbation theory. II. Eisenschitz-London type
- 1 January 1978
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 17 (1) , 18-23
- https://doi.org/10.1103/physreva.17.18
Abstract
An exchange perturbation theory is developed which is identical through first order in the primitive function with the Eisenschitz-London (EL) theory. It is shown that in higher orders, is different from the EL primitive function and from the primitive functions of related theories. The function is least distorted from the zeroth-order function , a product of functions for the subsystems when the interactions have been set equal to zero. The potential which distorts into is more thoroughly screened than in any other theory we have examined. We argue that this EL-type theory should be used when the unscreened interactions are strong.
Keywords
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