Metal nitrido- and oxo-complexes. Part I. Complexes of ruthenium and osmium
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1315-1320
- https://doi.org/10.1039/dt9730001315
Abstract
The preparation and physical properties of the new complexes Cs2[Ru(N)X5] and R[M(N)X4](M = Ru or Os; R = Ph4As or Bun 4N; X = Cl or Br) are described. New binuclear nitrido-bridged complexes of ruthenium(IV) with carbonyl, cyanide, and chelate ligands, the polymeric nitrido-bridged species [Os(N)Br4]n n– and [Os3(N)2X11 –(NH3)3]3–(X = Cl or Br), and oxo- and dioxo-complexes of ruthenium are also reported. The structures of the species are discussed on the basis of vibrational spectra and other properties.Keywords
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