Metal−Porphyrinogen Organometallic Chemistry: The Intramolecular Reactivity of η2-Acyls Bonded to Titanium(IV)−meso-Octaethyl Mono(pyridine)−Tris(pyrrole) and to Vanadium(III)−meso-Octaethyl Bis(pyridine)−Bis(pyrrole) Macrocycle
- 26 January 1999
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 18 (4) , 606-618
- https://doi.org/10.1021/om980888o
Abstract
No abstract availableKeywords
This publication has 40 references indexed in Scilit:
- A Novel Reaction Mode of a η2-Acyl Inserting into a C−C Bond: The Chemistry Associated with Vanadium(III) Bonded to a meso-Octaethyl Bis(pyridine)−Bis(pyrrole) MacrocycleOrganometallics, 1996
- Organometallic Chemistry of Titanium(IV) meso-Octaethylporphyrinogen Complex: Carrier Properties of Polar Organometallics and their Behavior in Insertion ReactionsOrganometallics, 1995
- Bifunctional Carriers of Organometallic Functionalities: Alkali-Metal-Zirconium-Hydrido, -Alkyl, and -Allyl Derivatives of meso-Octaethylporphyrinogen and Their Reaction with IsocyanidesOrganometallics, 1995
- Synthesis and Characterization of Mononuclear Octahedral Titanium(IV) Complexes Containing Ti:O, Ti(O2), and Ti(OCH3)x (x = 1-3) Structural UnitsInorganic Chemistry, 1994
- Zirconium-assisted homologation of pyrrole to pyridine in the conversion of meso-octaethylporphyrinogen into a meso-octaethyltrispyrrolemonopyridine macrocycle with carbon monoxide and the structure of the first zirconyl complexJournal of the American Chemical Society, 1993
- Addition and cycloaddition reactions of the nucleophilic oxo and sulfido complexes [tmtaa]Ti:X (X = O, S; tmtaa = dianion of 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine)Inorganic Chemistry, 1992
- Reduction of an electronically unsaturated transition-metal .eta.2-acyl complex. Arene formation from deoxygenative acyl coupling with a cyclopentadienyl ligandJournal of the American Chemical Society, 1990
- Chemistry of .eta.2-acyl, .eta.2-iminoacyl and related functional groupsChemical Reviews, 1988
- Reaction of Group 4 metal .eta.2-acyls with pyridine: formation of .alpha.,.alpha.-disubstituted-2,6-pyridinedimethoxide ligandsJournal of the American Chemical Society, 1986
- Carbon monoxide activation by biscyclopentadienyl complexes of Group 4 metals and actinides: .eta.2-acyl complexesJournal of the American Chemical Society, 1985